• 文献标题:   Sustainable Feasibility of the Environmental Pollutant Soot to Few-Layer Photoluminescent Graphene Nanosheets for Multifunctional Applications
  • 文献类型:   Article
  • 作  者:   TRIPATHI KM, SINGH A, BHATI A, SARKAR S, SONKAR SK
  • 作者关键词:   pollutant soot, watersoluble, fewlayer graphene nanosheet, selfpassivation, photoluminescent, chromium sensing
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Malaviya Natl Inst Technol
  • 被引频次:   26
  • DOI:   10.1021/acssuschemeng.6b01045
  • 出版年:   2016

▎ 摘  要

A simple and realistic approach to the utilization of waste "black carbon particulates of petrol soot" for the fabrication of few-layer water-soluble photoluminescent graphene nanosheets (wsGNS) is described herein. Direct transformation of pollutant soot to fluorescent nanocarbons can be a promising approach for providing some economic benefits along with a clean atmosphere. Oxidation of petrol soot resulted in the isolation of the watersoluble version of graphene nanosheets (GNS). Oxidative treatment is a key step in preventing the aggregation of the GNS and rendering them water-soluble. A high degree of "selfpassivation" on wsGNS provides evidence of the tunable photoluminescent emissions over a broad range of the visible spectrum with slight extension in the near-infrared region. The photoluminescent properties of wsGNS are used here for the selective detection of hexavalent chromium ions with a detection limit of 0.51 mu M and for imaging HeLa cells.