• 文献标题:   Catecholamine-Functionalized Reduced Graphene Oxide: A Scalable Carbon Host for Stable Cycling in Lithium-Sulfur Batteries
  • 文献类型:   Article
  • 作  者:   AHAD SA, KUMAR PR, KIM JH, KIM DJ, RAGUPATHY P, KIM DK
  • 作者关键词:   lithiumsulfur battery polydopamine, chemically reduced graphene oxide polysulfide, insitu uvvis spectroscopy
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Korea Adv Inst Sci Technol
  • 被引频次:   10
  • DOI:   10.1016/j.electacta.2017.06.042
  • 出版年:   2017

▎ 摘  要

The Lithium-Sulfur battery is a promising high performance battery candidate for large-scale application on account of its high theoretical specific capacity. However, it has come up short on delivering long cycle life mainly due to the formation of soluble polysulfides, which results in the loss of active material during redox processes. In this study, we prepared three different graphene oxide based carbon hosts - graphene oxide (GO), thermally reduced GO (t-rGO) and dopamine-assisted chemically reduced GO (c-rGO) - and investigated their physical and electrochemical properties as a sulfur cathode. We found significant absorbance of polysulfides on the c-rGO host, which provided stable discharge capacity of 601 mAh g(-1) at 0.5C for up to 300 cycles. This stable cycling behavior is further identified by in-situ UV-vis spectroscopy and ex-situ X-ray photoelectron spectroscopy, confirming the minimization of polysulfide dissolution toward the electrolyte through the adsorption of polydopamine coating. (C) 2017 Elsevier Ltd. All rights reserved.