• 文献标题:   Simple and affordable graphene nano-platelets and carbon nanocomposite surface decorated with cetrimonium bromide as a highly responsive electrochemical sensor for rutin detection
  • 文献类型:   Article
  • 作  者:   HAREESHA N, MANJUNATHA JG, ALOTHMAN ZA, SILLANPAA M
  • 作者关键词:   rutin, graphene nanoplatelet, carbon paste electrode, cetrimonium bromide, electrochemical analysi, biological food sample
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:  
  • 被引频次:   9
  • DOI:   10.1016/j.jelechem.2022.116388 EA MAY 2022
  • 出版年:   2022

▎ 摘  要

In this article, an economical, efficient, and unfussy nanocomposite sensor was equipped for the analysis of powerful antioxidant rutin (RTN). Due to the synergetic effect with more surface-active cites, cetrimonium bromide (CMB) was decorated on the surface of nanocomposite of graphene nano-platelets (GNPs) and carbon (CB) paste to attribute a superior electro-catalytic nature for RTN detection in phosphate buffer (PB) as a supporting electrolyte. The proposed CMB functionalized GNPs-CB composite paste electrode (CMB/GNPs-CBCPE) declining the material resistance and overpotential with rising the kinetic rate, peak currents, and material conductance towards the RTN detection. In the optimal experimental conditions, the analyzing efficiency of CMB/ GNPs-CBCPE was examined using the linear sweep voltammetry (LSV), cyclic voltammetry (CV), and differential pulse voltammetry (DPV) with a finer linear relation andthe corresponding limit of detection (LOD) values are found to be 0.041 mu M, 0.023 mu M, and 0.0027 mu M, respectively. The effect of some organic molecules and some metal ions on RTN detection at CMB/GNPs-CBCPE was studied with acceptable results. The sensitivity, selectivity, steadiness, repeatability, and reproducibility of the modified sensor were studied with decent results. The practicability of CMB/GNPs-CBCPE was verified by analyzing RTN in blood serum, urine, green tea, tomato, apple juice, and medicinal samples with adequate recoveries.