• 文献标题:   New strategy to prepare nitrogen self-doped graphene nanosheets by magnesiothermic reduction and its application in lithium ion batteries
  • 文献类型:   Article
  • 作  者:   WAN HR, HU XF
  • 作者关键词:   electrochemical performance, graphene, magnesiothermic reduction, lithium ion batterie, anode material
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   South China Univ Technol
  • 被引频次:   2
  • DOI:   10.1016/j.ijhydene.2019.07.207
  • 出版年:   2019

▎ 摘  要

Nitrogen self-doped graphene (N/G) nanosheets were prepared through magnesiothermic reduction of melamine. The obtained N/G features porous structure consisting of multi-layer nanosheets. The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Raman spectra and X-ray diffraction (XRD). As anode of lithium ion batteries (LIBs), it exhibits excellent reversible specific capacity of 1753 mAh g(-1) at 0.1 A g(-1) after 200 cycles. The reversible capacity can maintain at 1322 mAh g(-1) after 500 cycles at 2 A g(-1). At the same time, all results indicate remarkable cycle stability and rate performance as anode materials. Furthermore, this study demonstrates an economical, clean and facile strategy to synthesize N/G nanosheets from cheap chemicals with excellent electrochemical performance in LIBs. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.