• 文献标题:   Substrate-dependent plasmonic properties of supported graphene
  • 文献类型:   Article
  • 作  者:   CUPOLILLO A, POLITANO A, LIGATO N, PEREZ DMC, CHIARELLO G, CAPUTI LS
  • 作者关键词:   graphene, plasmonic propertie, ni 111, pt 111
  • 出版物名称:   SURFACE SCIENCE
  • ISSN:   0039-6028 EI 1879-2758
  • 通讯作者地址:   Univ Calabria
  • 被引频次:   14
  • DOI:   10.1016/j.susc.2014.11.002
  • 出版年:   2015

▎ 摘  要

Plasmon dispersion in epitaxial graphene systems has been studied by angle-resolved electron-energy-loss spectroscopy. In quasi-freestanding graphene/Pt(111), characterized by the survival of the Dirac cone of pristine graphene, the screening by the underlying substrate changes the dispersion of the intraband plasmon from square-root-like to an acoustic-like behavior. Likewise, the interband plasmon assumes a quadratic dispersion instead of the linear dispersion expected for free-standing graphene. By contrast, two-dimensional plasmon modes in graphene/Ni(111) are supported by interface states due to the strong hybridization between Ni d bands and it states of graphene. Both the intraband and the interband plasmon in graphene/Ni(111) show a square-root-like behavior dispersion, typical of a two-dimensional electron gas (2DEG). The intercalation of Cs atoms restores the linear plasmon dispersion of free-standing graphene. (C) 2014 Elsevier B.V. All rights reserved.