• 文献标题:   Preparation and Electrochemical Performance of Carbon Nanotubes/Graphene Oxide/Sulfur Complex Cathode Material
  • 文献类型:   Article
  • 作  者:   XU GY, DING B, NIE P, LUO HJ, ZHANG XG
  • 作者关键词:   lithiumsulfur battery, graphene oxide, carbon nanotube, composite, cycling performance
  • 出版物名称:   ACTA PHYSICOCHIMICA SINICA
  • ISSN:   1000-6818
  • 通讯作者地址:   Nanjing Univ Aeronaut Astronaut
  • 被引频次:   11
  • DOI:   10.3866/PKU.WHXB201301081
  • 出版年:   2013

▎ 摘  要

Three-dimensional (3D) hierarchical CNTs/GO/S ternary composites were prepared by solution-based reaction-deposition, using graphene oxide (GO) and carbon nanotubes (CNTs) as precursors. Scanning electron microscopy (SEM) and transmission electron microscope (TEM) indicated a uniform S coating on CNTs/GO which arose because of the large GO specific surface area. CNTs interspersed between the GO layers to form a 3D porous structure. Constant current charge-discharge tests showed that CNTs/GO/S composites had a high discharge capacity and excellent cycling stability, and delivered a high initial discharge capacity of 904 mAh . g(-1) at 1C rate. After 50 cycles at the same rate, the reversible capacity remained at 578 mAh . g(-1).