• 文献标题:   Cobalt telluride/reduced graphene oxide using as high performance counter electrode for dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   JIA JB, WU JH, DONG J, LIN JM
  • 作者关键词:   dyesensitized solar cell, counter electrode, cobalt telluride, reduced graphene oxide
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Huaqiao Univ
  • 被引频次:   18
  • DOI:   10.1016/j.electacta.2015.10.150
  • 出版年:   2015

▎ 摘  要

A cobalt telluride/reduced graphene oxide (CoTe/RGO) hybrid is synthesized by hydrothermal method and used as counter electrode in dye-sensitized solar cell (DSSC). The synthesized samples are characterized by field emission scanning electron microscopy and transmission electron microscope, which shows that CoTe/RGO has a larger specific surface area than CoTe. Cyclic voltammogram measurement indicates that CoTe/RGO electrode has larger current density and better electrocatalytic activity in the reduction of triiodidie than Pt electrode. Electrochemical impedance spectroscopy shows that CoTe/RGO electrode has lower charge-transfer resistance (2.94 V cm(2)). Owing to above advantages, the DSSC based on CoTe/RGO counter electrode achieves a high power conversion efficiency of 9.17%, outperforming that based on Pt counter electrode (8.17%). Therefore, inexpensive CoTe/RGO is a promising counter electrode to replace noble metal Pt. (C) 2015 Elsevier Ltd. All rights reserved.