• 文献标题:   Sustainable Preparation of Graphene Quantum Dots for Metal Ion Sensing Application
  • 文献类型:   Article
  • 作  者:   SAUD A, SALEEM H, MUNIRA N, SHAHAB AA, SIDDIQUI HR, ZAIDI SJ
  • 作者关键词:   graphene quantum dot, eucalyptus tree, hydrothermal treatment, leaf extract, photoluminescence, metal sensing
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3390/nano13010148
  • 出版年:   2023

▎ 摘  要

Over the past several years, graphene quantum dots (GQDs) have been extensively studied in water treatment and sensing applications because of their exceptional structure-related properties, intrinsic inert carbon property, eco-friendly nature, etc. This work reported on the preparation of GQDs from the ethanolic extracts of eucalyptus tree leaves by a hydrothermal treatment technique. Different heat treatment times and temperatures were used during the hydrothermal treatment technique. The optical, morphological, and compositional analyses of the green-synthesized GQDs were carried out. It can be noted that the product yield of GQDs showed the maximum yield at a reaction temperature of 300 degrees C. Further, it was noted that at a treatment period of 480 min, the greatest product yield of about 44.34% was attained. The quantum yields of prepared GQDs obtained after 480 min of treatment at 300 degrees C (named as GQD/300) were noted to be 0.069. Moreover, the D/G ratio of GQD/300 was noted to be 0.532 and this suggested that the GQD/300 developed has a nano-crystalline graphite structure. The TEM images demonstrated the development of GQD/300 with sizes between 2.0 to 5.0 nm. Furthermore, it was noted that the GQD/300 can detect Fe3+ in a very selective manner, and hence the developed GQD/300 was successfully used for the metal ion sensing application.