• 文献标题:   Influence of Annealing on Raman Spectrum of Graphene in Different Gaseous Environments
  • 文献类型:   Article
  • 作  者:   XIE WG, LAI X, WANG XM, WAN X, YAN ML, MAI WJ, LIU PY, CHEN J, XU JB
  • 作者关键词:   annealing, graphene, raman spectroscopy
  • 出版物名称:   SPECTROSCOPY LETTERS
  • ISSN:   0038-7010 EI 1532-2289
  • 通讯作者地址:   Sun Yat Sen Univ
  • 被引频次:   7
  • DOI:   10.1080/00387010.2013.809595
  • 出版年:   2014

▎ 摘  要

Graphene grown by a coronene (C-graphene) source is transferred to an SiO2 surface, and its Raman spectra are investigated in annealing environments of O-2, Ar, and N-2. An irreversible doping effect is observed in all the annealing environments, which is attributed to the enhancement of substrate doping. Compared with the mechanically exfoliated graphene on SiO2, stronger remnant stress remains in the transferred C-graphene, and wrinkles prevail on the surface. It is found that the defect density increases only after O-2 annealing, and the full width half maximum (FWHM) of the G and 2D bands in the Raman spectrum increases in all the annealing atmospheres. We suggest that the increase of FWHM is caused by the crystalline disorders.