• 文献标题:   Investigating the influence of surfactants on the stabilization of aqueous reduced graphene oxide dispersions and the characteristics of their composite films
  • 文献类型:   Article
  • 作  者:   FERNANDEZMERINO MJ, PAREDES JI, VILLARRODIL S, GUARDIA L, SOLISFERNANDEZ P, SALINASTORRES D, CAZORLAAMOROS D, MORALLON E, MARTINEZALONSO A, TASCON JMD
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223
  • 通讯作者地址:   CSIC
  • 被引频次:   65
  • DOI:   10.1016/j.carbon.2011.10.039
  • 出版年:   2012

▎ 摘  要

The stabilization of reduced graphene oxide (RGO) sheets in aqueous dispersion using a wide range of surfactants of anionic, non-ionic and zwitterionic type has been investigated and compared under different conditions of pH, surfactant and RGO concentration, or sheet size. The observed differences in the performance of the surfactants were rationalized on the basis of their chemical structure (e.g., alkylic vs. aromatic hydrophobic tail or sulfonic vs. carboxylic polar head), thus providing a reference framework in the selection of appropriate surfactants for the processing of RGO suspensions towards particular purposes. RGO-surfactant composite paper-like films were also prepared through vacuum filtration of the corresponding mixed dispersions and their main characteristics were investigated. The composite paper-like films were also electrochemically characterized. Those prepared with two specific surfactants exhibited a high capacitance in relation to their surfactant-free counterpart. (C) 2011 Elsevier Ltd. All rights reserved.