• 文献标题:   A Fully Integrated and Miniaturized Heavy-metal-detection Sensor Based on Micro-patterned Reduced Graphene Oxide
  • 文献类型:   Article
  • 作  者:   XUAN X, HOSSAIN MF, PARK JY
  • 作者关键词:  
  • 出版物名称:   SCIENTIFIC REPORTS
  • ISSN:   2045-2322
  • 通讯作者地址:   Kwangwoon Univ
  • 被引频次:   26
  • DOI:   10.1038/srep33125
  • 出版年:   2016

▎ 摘  要

For this paper, a fully integrated and highly miniaturized electrochemical sensor was designed and fabricated on a silicon substrate. A solvothermal-assisted reduced graphene oxide named TRGO was then successfully micro-patterned using a lithography technique, followed by the electrodeposition of bismuth (Bi) on the surface of the micro-patterned TRGO for the electrochemical detection of heavy metal ions. The fully integrated electrochemical micro-sensor was then measured and evaluated for the detection of cadmium and lead-heavy metal ions in an acetic-acid buffered solution using the square wave anodic stripping voltammetry (SWASV) technique. The fabricated micro-sensor exhibited a linear detection range of 1.0 mu g L-1 to 120.0 mu g L-1 for both of the metal ions, and detection limits of 0.4 mu g L-1 and 1.0 mu g L-1 were recorded for the lead and cadmium (S/N = 3), respectively. Drinking-water samples were used for the practical assessment of the fabricated micro-sensor, and it showed an acceptable detection performance regarding the metal ions.