• 文献标题:   Novel one-pot hydrothermal fabrication of cuprous oxide-attapulgite/graphene for non-enzyme glucose sensing
  • 文献类型:   Article
  • 作  者:   ZHANG SS, ZHANG GL, HE P, LEI W, DONG FQ, YANG DM, SUO ZR
  • 作者关键词:  
  • 出版物名称:   ANALYTICAL METHODS
  • ISSN:   1759-9660 EI 1759-9679
  • 通讯作者地址:   Southwest Univ Sci Technol
  • 被引频次:   7
  • DOI:   10.1039/c4ay03001j
  • 出版年:   2015

▎ 摘  要

A novel cuprous oxide-attapulgite/graphene based non-enzyme biosensor was constructed successfully for the detection of glucose. Graphite oxide and Cu2+-functionalized attapulgite were simultaneously reduced by hydrazine hydrate under mild hydrothermal conditions in one pot, and subsequently dried at 80 degrees C in air to obtain cuprous oxide-attapulgite/graphene composites. The composites were characterized by XRD, Raman spectroscopy, EDX and SEM. Due to the synergistic effect of cuprous oxide-attapulgite and graphene, the as-prepared composites presented excellent electrocatalytic performances. The cuprous oxide-attapulgite/graphene modified electrode exhibited sensitive linear amperometric responses to glucose in the concentration range of 4.0 x 10 (5) M to 3.0 x 10 (3) M (R = 0.996), and the detection limit was calculated to be 2.1 x 10(-6) M. The as-prepared modified electrode was highly selective for glucose in the presence of common interfering species in biological fluids, such as dopamine, ascorbic acid and uric acid.