• 文献标题:   Two-Dimensional Mn-Co LDH/Graphene Composite towards High-Performance Water Splitting
  • 文献类型:   Article
  • 作  者:   BAO J, XIE JF, LEI FC, WANG ZL, LIU WJ, XU L, GUAN ML, ZHAO Y, LI HM
  • 作者关键词:   ultrathin structure, oxygen evolution reaction, graphene, twodimensional, layered double hydroxide
  • 出版物名称:   CATALYSTS
  • ISSN:   2073-4344
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   4
  • DOI:   10.3390/catal8090350
  • 出版年:   2018

▎ 摘  要

The oxygen evolution reaction (OER) is a complex multi-step four-electron process showing sluggish kinetics. Layered double hydroxides (LDH) were reported as promising catalysts for the OER, but their low electrical conductivity restricts their widespread applications. To overcome this problem, a composite material containing Mn-Co LDH ultrathin nanosheet and highly conductive graphene was synthesized for the first time. Benefited from the high electrocatalytic activity and the superior charge transfer ability induced by these components, the new material shows superior OER activity. Used as the OER catalyst, a high current density of 461 mA cm(-2) at 2.0 V vs. RHE (reversible hydrogen electrode) was measured besides shows a low overpotential of 0.33 V at 10 mA cm(-2). Moreover, the new composite also shows a superior bifunctional water splitting performance as catalyst for the OER and HER (hydrogen evolution reaction) catalysts. Our results indicate that the presented material is a promising candidate for water splitting which is cheap and efficient.