• 文献标题:   Plasma-functionalized exfoliated multilayered graphene as cement reinforcement
  • 文献类型:   Article
  • 作  者:   DELA VEGA MSDC, VASQUEZ MR
  • 作者关键词:   plasma functionalization, multilayered graphene, graphene exfoliation, cement composite, nanoreinforcement
  • 出版物名称:   COMPOSITES PART BENGINEERING
  • ISSN:   1359-8368 EI 1879-1069
  • 通讯作者地址:   Univ Philippines
  • 被引频次:   9
  • DOI:   10.1016/j.compositesb.2018.12.055
  • 出版年:   2019

▎ 摘  要

A fast, facile, nonhazardous, environment-friendly, and high yield process was developed for the plasma treatment of graphite particles and the production of plasma-functionalized multilayered graphene (pf-MLG). Graphite particles (< 20 mu m) were functionalized using a subatmospheric 13.56 MHz radio frequency-excited oxygen plasma followed by liquid-phase exfoliation to produce pf-MLG with a high aspect ratio (> 2585) with < 20 graphene layers. The exfoliated graphene also exhibited high dispersibility in water after plasma functionalization without the use of surfactants. The pf-MLG nanoflakes were incorporated into a cement mixture with 0.1 and 0.5 wt% pf-MLG loading. A 56% increase in compressive strength of cement mortars was achieved for the 0.5 wt% pf-MLG after 28 days curing. This is attributed to the strong interfacial interaction between graphene and the cement matrix and the promotion of hydration. The highly scalable process of pf-MLG-reinforced cement will make a positive impact on the environment, especially in the construction industry.