• 文献标题:   Nanoarchitectured Co3O4/reduced graphene oxide as anode material for lithium-ion batteries with enhanced cycling stability
  • 文献类型:   Article
  • 作  者:   CHEN ZH, GAO Y, CHEN XY, XING BL, ZHANG CX, WANG S, LIU T, LIU Y, ZHANG ZY
  • 作者关键词:   cobalt oxide, reduced graphene oxide, hydrothermal synthesi, lithiumion batterie, nanoarchitectured
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Henan Polytech Univ
  • 被引频次:   3
  • DOI:   10.1007/s11581-019-03134-x
  • 出版年:   2019

▎ 摘  要

In this paper, we report on the synthesis of a nanoarchitectured Co3O4/reduced graphene oxide (Co3O4/rGO) composite by a one-pot method. The results of X-ray diffraction and HRTEM demonstrate that the pristine Co3O4 and Co3O4/rGO powder composites consist of a nanostructured powder with high crystallinity and the nanoarchitectured Co3O4 was completely coated by the rGO. As an anode for lithium-ion batteries, the nanocomposite exhibits improved electrochemical properties, with an initial capacity of 1298 mAh g(-1) at a rate of 0.1 C, and excellent cyclability up to 200 cycles at a rate of 1 C compared with the pristine Co3O4. These results can be attributed to the higher specific surface area, lower interface transfer resistance, and fast reaction kinetics of the composite electrode.