• 文献标题:   Fluorination of graphene oxide at ambient conditions
  • 文献类型:   Article
  • 作  者:   LIU Y, CHEN JN, LI X, SHI YT, CHEN MM, CAO DW
  • 作者关键词:   fluorination, graphene oxide, ambient condition, reaction barrier, magnetic inducing efficiency
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   0
  • DOI:   10.1016/j.diamond.2018.11.010
  • 出版年:   2019

▎ 摘  要

Fluorination is a feasible method to modify the properties of graphene. However, the fluorination methods still meet different limitations such as inconvenient, low-yield, high-cost, etc. Here, a room-temperature method at ambient conditions was presented to synthesize fluorinated graphene oxide (FGO). The obtained FGO had the F content of ca. 28.6 at%. The mechanism of the reaction at ambient conditions was discussed by theoretical calculations, which showed that the oxygen groups facilitated to generate stable C-F bonds by overcoming a low reaction barrier. This work provides an easy synthesis of FGO, broadening the applications of functionalized graphene, for example, increasing the magnetic inducing efficiency to ca. 1.03 x 10(-2) mu(B)/F.