• 文献标题:   Optimization of UHMWPE/graphene nanocomposite preparation by single-supported Ziegler-Natta catalytic system via RSM
  • 文献类型:   Article
  • 作  者:   SHAFIEE M, AKBARI A
  • 作者关键词:   graphene, polymerization, response surface methodology rsm, uhmwpe, zieglernatta
  • 出版物名称:   POLYMERS FOR ADVANCED TECHNOLOGIES
  • ISSN:   1042-7147 EI 1099-1581
  • 通讯作者地址:   Jundi Shapur Univ Technol
  • 被引频次:   0
  • DOI:   10.1002/pat.4297
  • 出版年:   2018

▎ 摘  要

In this study, the preparation of ultra-high molecular weight polyethylene/graphene nanocomposite was carried out using single-supported Ziegler-Natta catalyst, and the operational conditions were optimized via response surface methodology. For this purpose, the effect of 3 parameters, monomer pressure, temperature, and molar ratio of [Al] respect to [Ti] on the catalyst productivity and molecular weight of the synthesized nanocomposite polymer, was investigated using the Box-Behnken experimental design at 3 levels. Monomer pressure, temperature, and molar ratio of [Al] respect to [Ti] were considered as independent variables and catalyst productivity and molecular weight as dependent variables. The highest catalyst productivity and molecular weight were equal to 923 (grPE/mmolTi.h) and 2.04 (million gr/mol), respectively, which were obtained under optimal reaction conditions: temperature of 60 degrees C, pressure of 8bar, and molar ratio of 185. Finally, in order to investigate the morphology and nanoparticle dispersion in polymer matrix, scanning electron microscope and X-ray diffraction were used. The results indicate the homogenous dispersion of graphene nanoparticles in polymer matrix.