• 文献标题:   Selective surface functionalization at regions of high local curvature in graphene
  • 文献类型:   Article
  • 作  者:   WU QZ, WU YP, HAO YF, GENG JX, CHARLTON M, CHEN SS, REN YJ, JI HX, LI HF, BOUKHVALOV DW, PINER RD, BIELAWSKI CW, RUOFF RS
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Univ Texas Austin
  • 被引频次:   85
  • DOI:   10.1039/c2cc36747e
  • 出版年:   2013

▎ 摘  要

Monolayer graphene was deposited on a Si wafer substrate decorated with SiO2 nanoparticles (NPs) and then exposed to aryl radicals that were generated in situ from their diazonium precursors. Using micro-Raman mapping, the aryl radicals were found to selectively react with the regions of graphene that covered the NPs. The enhanced chemical reactivity was attributed to the increased strain energy induced by the local mechanical deformation of the graphene.