• 文献标题:   High-performance symmetric supercapacitor device based on carbonized iron-polyaniline/nickel graphene foam
  • 文献类型:   Article
  • 作  者:   RANTHO MN, MADITO MJ, MANYALA N
  • 作者关键词:   supercapacitor, symmetric device, negative electrode, pani, graphene foam
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Univ Pretoria
  • 被引频次:   6
  • DOI:   10.1016/j.jallcom.2019.152993
  • 出版年:   2020

▎ 摘  要

The carbonized iron-polyaniline/nickel graphene foam (C-Fe/PANI/Ni-GF) electrode was prepared by pasting a mixture of iron-polyaniline (Fe/PANI) on nickel graphene foam (Ni-GF) and carbonized under the nitrogen. For electrochemical characterization, the as-prepared electrode material was evaluated in both three and two-electrode (i.e. symmetric) cell configurations using 1 M NaNO3 electrolyte. The symmetric device exhibited a maximum energy density of 68.0 W h kg(-1) and power density of 718.2 W kg(-1), at a specific current of 1.0 A g(-1) and the maximum potential of 1.7 V. The device further displayed long-term cycling stability with capacity retention of 91% over 10 000 galvanostatic charge-discharge cycles at 5 A g(-1). The stability of the device was also tested using the voltage holding and self-discharge approach whereby a slow-discharging process was observed, which suggests the practical application of the device. (C) 2019 Elsevier B.V. All rights reserved.