• 文献标题:   OWL-Based Nanomasks for Preparing Graphene Ribbons with Sub-10 nm Gaps
  • 文献类型:   Article
  • 作  者:   ZHOU XZ, SHADE CM, SCHMUCKER AL, BROWN KA, HE S, BOEY F, MA J, ZHANG H, MIRKIN CA
  • 作者关键词:   graphene, nanogap, nanoribbon, onwire lithography, silicon nanostructure
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Northwestern Univ
  • 被引频次:   9
  • DOI:   10.1021/nl302171z
  • 出版年:   2012

▎ 摘  要

We report a simple and highly efficient method for creating graphene nanostructures with gaps that can be controlled on the sub-10 nm length scale by utilizing etch masks comprised of electrochemically synthesized multisegmented metal nanowires. This method involves depositing striped nanowires with Au and Ni segments on a graphene-coated substrate, chemically etching the Ni segments, and using a reactive ion etch to remove the graphene not protected by the remaining Au segments. Graphene nanoribbons with gaps as small as 6 nm are fabricated and characterized with atomic force microscopy, scanning electron microscopy, and Raman spectroscopy. The high level of control afforded by electrochemical synthesis of the nanowires allows us to specify the dimensions of the nanoribbon, as well as the number, location, and size of nanogaps within the nanoribbon. In addition, the generality of this technique is demonstrated by creating silicon nanostructures with nanogaps.