• 文献标题:   Spatially resolved raman spectroscopy of single- and few-layer graphene
  • 文献类型:   Article
  • 作  者:   GRAF D, MOLITOR F, ENSSLIN K, STAMPFER C, JUNGEN A, HIEROLD C, WIRTZ L
  • 作者关键词:  
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984
  • 通讯作者地址:   ETH
  • 被引频次:   1814
  • DOI:   10.1021/nl061702a
  • 出版年:   2007

▎ 摘  要

We present Raman spectroscopy measurements on single- and few-layer graphene flakes. By using a scanning confocal approach, we collect spectral data with spatial resolution, which allows us to directly compare Raman images with scanning force micrographs. Single-layer graphene can be distinguished from double- and few-layer by the width of the D' line: the single peak for single-layer graphene splits into different peaks for the double-layer. These findings are explained using the double-resonant Raman model based on ab initio calculations of the electronic structure and of the phonon dispersion. We investigate the D line intensity and find no defects within the flake. A finite D line response originating from the edges can be attributed either to defects or to the breakdown of translational symmetry.