• 文献标题:   Effects of electron-transfer chemical modification on the electrical characteristics of graphene
  • 文献类型:   Article
  • 作  者:   FAN XY, NOUCHI R, YIN LC, TANIGAKI K
  • 作者关键词:  
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Tohoku Univ
  • 被引频次:   28
  • DOI:   10.1088/0957-4484/21/47/475208
  • 出版年:   2010

▎ 摘  要

Because of the large reactivity of single layer graphene to electron-transfer chemistries, 4-nitrobenzene diazonium tetrafluoroborate is employed to modify the electrical properties of graphene field-effect transistors. After modification, the transfer characteristics of chemically modified graphene show a reduction in the minimum conductivity, electron-hole mobility asymmetry, a decrease in the electron/hole mobility, and a positive shift of the charge neutrality point with broadening of the minimum conductivity region. These phenomena are attributed to a dediazoniation reaction and the adsorbates on the graphene surface.