• 文献标题:   Enhanced photocatalytic degradation of metronidazole by TiO2 decorated on magnetic reduced graphene oxide: Characterization, optimization and reaction mechanism studies
  • 文献类型:   Article
  • 作  者:   BASHIRI F, KHEZRI SM, KALANTARY RR, KAKAVANDI B
  • 作者关键词:   water pollution, photocatalytic degradation, metronidazole, magnetic composite, advanced oxidation proces
  • 出版物名称:   JOURNAL OF MOLECULAR LIQUIDS
  • ISSN:   0167-7322 EI 1873-3166
  • 通讯作者地址:   Islamic Azad Univ
  • 被引频次:   1
  • DOI:   10.1016/j.molliq.2020.113608
  • 出版年:   2020

▎ 摘  要

In this work, the TiO2 decorated magnetic reduced graphene oxide was fabricated by the hydrothermal method. The characterization of prepared composite was studied by XRD, FT-IR, SEM, EDX, BET, and TGA techniques. Both the magnetization of TiO2 by Fe3O4 nanoparticles and then its decorating on rGO surface were confirmed using characterization tests. The photocatalytic efficacy of the provided samples was defined via the degradation of metronidazole (MNZ) under visible light irradiation. The operational parameters' effect, including pH, catalyst dosage, initial MNZ concentration, rGO, and TiO2, was evaluated. The results indicated that the maximum degradation rate of MNZ (0.0092 min(-1)) was obtained for 0.75 g composite containing 4% rGO and 5% TiO2 at pH = 5 and MNZ concentration of 20 mg/L. MNZ and TOC were eliminated completely at optimum operational conditions within 120 and 250 min reaction times, respectively. The quenching test revealed that O-2(center dot-) acted as dominant radical in the degradation process. (C) 2020 Elsevier B.V. All rights reserved.