• 文献标题:   Efficient Removal of Cobalt(II) and Strontium(II) Metals from Water using Ethylene Diamine Tetra-acetic Acid Functionalized Graphene Oxide
  • 文献类型:   Article
  • 作  者:   AMER H, MOUSTAFA WM, FARGHALI AA, EL ROUBY WMA, KHALIL WF
  • 作者关键词:   strontium, cobalt, graphene oxide, edta, adsorption
  • 出版物名称:   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
  • ISSN:   0044-2313 EI 1521-3749
  • 通讯作者地址:   NRRA
  • 被引频次:   7
  • DOI:   10.1002/zaac.201700318
  • 出版年:   2017

▎ 摘  要

Graphene oxide (GO) with high specific surface area was prepared and functionalized with ethylene diamine tetra-acetic acid (EDTA). The as-prepared GO and the functionalized one (GO-EDTA) were characterized using high resolution transmission electron microscopy (HRTEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and Raman spectroscopy. The as-prepared and EDTA funcationalized GO were applied as adsorbent to remove strontium(II) and cobalt(II) from water. The results indicated that the prepared materials are efficient adsorbents for strontium(II) and cobalt(II) removal. The adsorption of Co-II and Sr-II under effects of contact time, temperature, and pH was investigated It is concluded that the maximum adsorption capacities of GO for Co-II and Sr-II were about 168 and 140 mgg(-1), whereas of GO-EDTA the values were about 197 and 158 mgg(-1), respectively. It is indicated that pH 6 and temperature 40 degrees C are the best condition for Co-II and Sr-II removal from water. The application of Langmuir and Freundlich isotherms indicated that Langmuir isotherm is best fit for Co-II and Sr-II equilibrium adsorption. Adsorption kinetics were studied by applying pseudo first-order, pseudo second-order, and intraparticle diffusion models on the experimental data. The results proved that pseudo second-order model is the best represented adsorption kinetics. Appling the intraparticle diffusion regressions on the experimental data indicated that intraparticle diffusion involved in adsorption process, which was not the only rate-controlling step.