• 文献标题:   Holey Graphene as a Weed Barrier for Molecules
  • 文献类型:   Article
  • 作  者:   GETHERS ML, THOMAS JC, JIANG S, WEISS NO, DUAN X, GODDARD WA, WEISS PS
  • 作者关键词:   nanoscience, graphene, mask, chemical patterning, selfassembly, scanning tunneling microscopy
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Univ Calif Los Angeles
  • 被引频次:   23
  • DOI:   10.1021/acsnano.5b03936
  • 出版年:   2015

▎ 摘  要

We demonstrate the use of "holey" graphene as a mask against molecular adsorption. Prepared porous graphene is transferred onto a Au{111} substrate, annealed, and then exposed to dilute solutions of 1-adamantanethiol. In the pores of the graphene lattice, we find islands of organized, self-assembled molecules. The bare Au in the pores can be regenerated by postdeposition annealing, and new molecules can be self-assembled in the exposed Au region. Graphene can serve as a robust, patternable mask against the deposition of self-assembled monolayers.