• 文献标题:   Preparation of chemically functionalized graphene with excellent dispersibility and tribological properties as lubricant additives by microwave-assisted ball milling
  • 文献类型:   Article
  • 作  者:   WANG SY, LIANG Z, LIU L, CAO YC, CHENG YL, CHEN D
  • 作者关键词:   graphene additive, chemical functionalization, microwaveassisted ball milling, dispersion, tribological propertie
  • 出版物名称:   JOURNAL OF MOLECULAR LIQUIDS
  • ISSN:   0167-7322 EI 1873-3166
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.molliq.2021.117929 EA NOV 2021
  • 出版年:   2021

▎ 摘  要

Despite being regarded as one of the most promising lubricant additives, poor dispersion remains a huge obstacle for graphene applications. To solve this problem, the traditional method is to modify graphene with chemical functionalization under harsh conditions. The present investigation prepared modified reduced graphene oxide by the traditional method (MRGO-1) and microwave-assisted ball milling (MRGO-2). The chemical and structural features of MRGO-1 and MRGO-2 are examined by SEM, TEM, XRD, Raman, FTIR, and TGA analyses. The results indicate the microwave-assisted ball milling enables MRGO-2 to be more efficiently dispersed and functionalized than MRGO-1. MRGO-1 and MRGO-2 were introduced into poly alpha-olefin oil (PAO6) as lubricant additives, and the dispersion and tribological performances were tested. Compared with MRGO-1, the dispersion stability of MRGO-2 is increased by 73.8%. Due to its excellent dispersion performance, MRGO-2 can consistently maintain a low friction coefficient during the friction process, and the average friction coefficient is 49.01% lower than that of MRGO-1. Furthermore, the EDS on the worn area demonstrates the most efficient transfer of MRGO-2 on the friction contact interfaces. Finally, the reasons for the improvement in dispersion stability and tribological properties of graphene by microwave-assisted ball milling are explained. (C) 2021 Elsevier B.V. All rights reserved.