• 文献标题:   Dense Reduced Graphene Oxide Films Obtained by Pressing Create Stable and Compact Capacitive Energy Storage
  • 文献类型:   Article
  • 作  者:   LIN D, TANG ZH, PAN QJ, ZHANG SP, HUO DX, YAN SS, HAN FM
  • 作者关键词:   graphene hydrogel film, supercapacitor, volumetric energy density, cycling stability, power density
  • 出版物名称:   CHEMELECTROCHEM
  • ISSN:   2196-0216
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   0
  • DOI:   10.1002/celc.202000246 EA APR 2020
  • 出版年:   2020

▎ 摘  要

It is generally believed that the re-stacking of reduced graphene oxide (rGO) sheets limits the electrochemical energy storage. Therefore, rGO based electrodes are usually designed to be non-compact porous and fluffy structures. However, fluffy structures could reduce the conductance, structure stability, and cycling stability of electrodes. Here, to balance the contradiction, three electrodes with different compactness were studied. Amazingly, dense rGO hydrogel films (DrGO-HF) achieved by simply pressing filtrated rGO films, show highly stable (92 % capacitance retention after 250 000 cycles) and high-performance compact capacitive energy storage, which can be attributed to the structural stability and electrical conductivity enhanced by the close contact between graphene sheets. This study clarifies the scientific fact that the re-stacking of rGO sheets would not degrade the electrochemical energy storage performances, which is of great significance for the design and preparation of supercapacitor electrodes with high volumetric energy density.