• 文献标题:   Ultrafast preparation of three-dimensional porous tin-graphene composites with superior lithium ion storage
  • 文献类型:   Article
  • 作  者:   ZHU JS, WANG DL, CAO LB, LIU TF
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   42
  • DOI:   10.1039/c4ta02021a
  • 出版年:   2014

▎ 摘  要

Three-dimensional porous Sn-graphene composites have been prepared on Ni foam by an easy, binder-free, low-cost and ultrafast electrophoretic deposition method. The structure and morphology of the as-prepared composite material are characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, high resolution transmission electron microscopy, field emission scanning electron microscopy and elemental analysis. The lithium storage performance of the three-dimensional porous Sn-graphene anode is evaluated by cyclic voltammetry, galvanostatic charge-discharge cycling, and electrochemical impedance spectroscopy measurements. Results show that the composite material with a graphene content of 6.1 wt% delivers a reversible capacity of 552 mA h g(-1) after 200 cycles at a current density of 500 mA g(-1). The synthetic approach presented in this work may provide a facile strategy for the preparation of three-dimensional porous metal-graphene composites.