• 文献标题:   In2S3 nanosheets array anchored on reduced graphene oxide as high-performance anode for sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   SHAO HJ, FENG XM, LIU YP, ZHANG Y, HAN LX, GAO Y, WANG N, ZHANG XT, JIANG FY, DONG CF
  • 作者关键词:   in2s3/rgo, nanosheets array, sodiumion battery, anode, ultrahigh performance
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.jallcom.2021.165506
  • 出版年:   2022

▎ 摘  要

Indium sulfide has been proved to be a high-capacity anode material for sodium-ion batteries, but severe volume changes and low electrical conductivity limit its practical electrochemical performance. Based on this, graphene (RGO)-loaded In2S3 nanosheets array composites (In2S3/RGO) are synthesized by a simple reflux method to enhance charge transfer and ion diffusion kinetics as well as the structural stability of electrodes. By optimizing the amount of RGO, In2S3/RGO exhibits a high specific capacity of 450 mAh g(-1) at 2 A g(-1) after 500 cycles with a capacity fading of 0.04% per cycle (from 2nd to 500th) and remarkable rate performance of 460 mAh g(-1) at 12 A g(-1). The XRD and HRTEM analysis indicates that In2S3/RGO is based on a conversion mechanism for energy storage. Furthermore, the In2S3/RGO//Na3V2(PO4)(3) full cell is successfully fabricated. The simple and efficient synthesis method and the excellent sodium storage properties offer great prospects for the practical application of In2S3/RGO. (C) 2022 Published by Elsevier B.V.