• 文献标题:   Facile fabrication of highly catalytic-active Ag2CO3/AgBr/graphene oxide ternary composites towards the photocatalytic wastewater treatment
  • 文献类型:   Article, Early Access
  • 作  者:   SI MZ, WANG WG, GUAN QF, ZHANG HY, PUTTASWAMY M
  • 作者关键词:   ag2co3, graphene, ternary composite, photocatalysi, free radical
  • 出版物名称:   ENVIRONMENTAL SCIENCE POLLUTION RESEARCH
  • ISSN:   0944-1344 EI 1614-7499
  • 通讯作者地址:   Guangdong Univ Technol
  • 被引频次:   0
  • DOI:   10.1007/s11356-020-10740-0 EA SEP 2020
  • 出版年:  

▎ 摘  要

Ag2CO3/AgBr/graphene oxide (Ag2CO3/AgBr/GO) ternary composites with different percentages of GO were fabricated by a facile co-precipitation strategy. The composites were characterized in the aspect of phase composition, light absorption performance, and micromorphology etc. The activity of the composites was studied by photocatalytic degradation of colored organic dye (rhodamine B, RhB) and colorless organics (phenol) under the shine of visible light. The optimized Ag2CO3/AgBr/GO-7.5 composites revealed the most excellent photocatalytic activity, which exhibited an apparent reaction rate constant exceeding that of pristine AgBr and Ag(2)CO(3)by a factor of 107 and 5.63, respectively. The outstanding performance can be attributed to the effective separation of electrons and holes as well as the strong light absorption ability resulting from the Ag2CO3/AgBr/GO heterostructure. Moreover, it was verified that h(+)and center dot O(2)(-)were two major active substances responsible for the decomposition of organic pollutants according to the free radical-trapping experiments. Besides, a probable reaction mechanism referring to the charge transfer and separation in the composites was proposed and discussed in detail.