• 文献标题:   Variation in the c-axis conductivity of multi-layer graphene due to H-2 exposure
  • 文献类型:   Article
  • 作  者:   KIM J, KWAK CH, JUNG W, HUH YS, KIM BH
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Incheon Natl Univ
  • 被引频次:   4
  • DOI:   10.1039/c6cp01745b
  • 出版年:   2016

▎ 摘  要

The variation of the c-axis conductivity of a multilayer graphene (MLG) as a function of H-2 pressure from vacuum to 20 bar has been investigated. MLG was connected to the electrodes vertically using a wet transfer process. After exposure to H-2 gas pressure up to 20 bar, the chemisorption of dissociated atomic hydrogen on MLG affects its electrical and structural properties. The formation of C-H bonds causes a decoupling of graphene layers, and then interferes with charge transfer through the out of plane. As a result, the c-axis conductivity decreases. Furthermore, the electron doping effect and the decoupling of the layers were confirmed using Raman spectroscopy. Hydrogenated carbons induce a defect structure of MLG which results in the expansion of layers. We observed a 43.54% increase in the thickness of the MLG after H-2 exposure using atomic force microscopy.