• 文献标题:   Effect of Boron-Doping on the Graphene Aerogel Used as Cathode for the Lithium Sulfur Battery
  • 文献类型:   Article
  • 作  者:   XIE Y, MENG Z, CAI TW, HAN WQ
  • 作者关键词:   lithiumsulfur batterie, borondoped graphene aerogel, porous structure, chemical adsorption, electrochemical performance
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   83
  • DOI:   10.1021/acsami.5b08129
  • 出版年:   2015

▎ 摘  要

A porous interconnected 3D boron-doped graphene aerogel (BGA) was prepared via a one-pot hydrothermal treatment. The BGA material was first loaded with sulfur to serve as cathode in lithiumsulfur batteries. Boron was positively polarized on the graphene framework, allowing for chemical adsorption of negative polysufide species. Compared with nitrogen-doped and undoped graphene aerogel, the BGA-S cathode could deliver a higher capacity of 994 mA h g(-1) at 0.2 C after 100 cycles, as well as an outstanding rate capability, which indicated the BGA was an ideal cathode material for lithiumsulfur batteries.