• 文献标题:   Preparation, Characterization, and Catalytic Properties of Pd-Graphene Quantum Dot Catalysts
  • 文献类型:   Article
  • 作  者:   KIM J, LIM J, KIM JD, CHOI MY, LEE S, CHOI HC
  • 作者关键词:   pd nanoparticle, graphene quantum dot, heterogeneous organocatalysi, heck crosscoupling reaction, decarboxylative crosscoupling reaction
  • 出版物名称:   CATALYSTS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.3390/catal12060619
  • 出版年:   2022

▎ 摘  要

In this study, Pd-graphene quantum dot (Pd-GQD) catalysts were prepared by depositing Pd nanoparticles onto functionalized GQD surfaces, and their morphology and elemental composition were characterized using transmission electron microscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy. The as-prepared Pd-GQD was subsequently employed as a catalyst for the Heck and decarboxylative cross-coupling reactions and was found to exhibit higher catalytic activity than other reference systems. The expanded substrate scope of various substituted aryl iodides further proved that the GQD is an effective support for preparing new heterogeneous catalysts with improved catalytic performances.