• 文献标题:   Effects of ZnO Quantum Dots Decoration on the Field Emission Behavior of Graphene
  • 文献类型:   Article
  • 作  者:   SUN L, ZHOU XT, LIN ZX, GUO TL, ZHANG YG, ZENG YZ
  • 作者关键词:   zno quantum dot, graphene, field emission, hybrid, firstprinciple density functional calculation
  • 出版物名称:   ACS Applied Materials Interfaces
  • ISSN:   1944-8244
  • 通讯作者地址:   Fuzhou Univ
  • 被引频次:   6
  • DOI:   10.1021/acsami.6b10454
  • 出版年:   2016

▎ 摘  要

ZnO quantum dots (QDs) have been decorated on graphene deposited on patterned Ag electrodes as a field emission cathode by a solution process. Effects of ZnO QDs on the field emission behavior of graphene are studied by experiment and first-principles calculations. The results indicate that the attachment of ZnO QDs with a C atom leads to the enhancement of electron emission from graphene, which is mainly attributed to the reduction of the work function and ionization potential, and the increase of the Fermi level of graphene after the decoration. A change in the local density distribution and the density of states near the Fermi level may also account for this behavior. Our study may help to develop new field emission composites and expand ZnO QDs in applications for electron emission devices as well.