• 文献标题:   Functionalized Graphene from Electrochemical Exfoliation of Graphite toward Improving Lubrication Function of Base Oil
  • 文献类型:   Article
  • 作  者:   ZHANG CF, ZHANG XJ, ZHANG W, ZHAO Z, FAN XQ
  • 作者关键词:   electrochemical exfoliation, graphene, ionic liquid, lubricant additive, tribological propertie
  • 出版物名称:   LUBRICANTS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3390/lubricants11040166
  • 出版年:   2023

▎ 摘  要

Electrochemical exfoliation of graphene is an environmentally friendly method, which enables mass production. Herein, three ionic liquids (ILs) with the same imidazole cation were used to exfoliate graphite into functionalized graphene, as a lubricant additive in an acetonitrile solution. Chemical and structural characterization revealed the relationship between the functionalization density of graphene and the concentration of IL, showing higher concentrations with higher densities. The exfoliated graphene hybrid oil displayed good dispersion because of a high functionalization density. More importantly, the different anions affected the tribological properties of the exfoliated graphene. Among them, the exfoliated graphene with 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIm][PF6]) possessed the best tribological performance, and the average friction coefficient and wear volume were reduced by 32% and 39%, respectively. Through the characterization of worn surfaces and wear debris, the lubrication mechanism and structural evolution of the functionalized graphene were illustrated in detail. The good lubrication function was attributed to the formation of a tribo-film and the disorder transformation of the graphene structure. The simultaneous exfoliation and functionalization of graphene offers a promising advanced lubricant for industrial fabrication.