• 文献标题:   Visible-Light Photocatalytic Hydrogen Generation by Using Dye-Sensitized Graphene Oxide as a Photocatalyst
  • 文献类型:   Article
  • 作  者:   LATORRESANCHEZ M, LAVORATO C, PUCHE M, FORNES V, MOLINARI R, GARCIA H
  • 作者关键词:   dyes/pigment, graphene, photochemistry, visible light, water splitting
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539
  • 通讯作者地址:   Univ Politecn Valencia
  • 被引频次:   46
  • DOI:   10.1002/chem.201202372
  • 出版年:   2012

▎ 摘  要

Dye-sensitized graphene oxide is able to generate hydrogen from water/methanol mixtures (80:20) by using visible or solar light. The most efficient photocatalyst tested contained a tris(2,2-bipyridyl) ruthenium(II) complex incorporated in the interlayer spaces of a few layers of graphene oxide with a moderate degree of oxidation. The graphene oxide-based photocatalyst does not contain noble metals and we have determined that it is two orders of magnitude more active than catalysts based on conventional titania.