• 文献标题:   N-doped Carbon Framework/Reduced Graphene Oxide Nanocomposite as a Sulfur Reservoir for Lithium-Sulfur Batteries
  • 文献类型:   Article
  • 作  者:   LEE J, PARK SK, PIAO Y
  • 作者关键词:   melamine foam, reduced graphene oxide, hetero atom, lithiumsulfur batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   16
  • DOI:   10.1016/j.electacta.2016.11.110
  • 出版年:   2016

▎ 摘  要

In this study, by using commercial melamine foam as a starting material, we report a facile method to prepare N-doped carbon framework loaded with graphene (NCF-G), in which graphene nanosheets are homogeneously coated on the N-doped carbon framework. After sulfur is infused into this composite, the electrode delivers an initial capacity of 1,359.7 mA h g (1) at 0.1C (1st cycle), and maintains a specific capacity of 629.3 mA h g (1) for 150 cycles at 0.5C for lithium-sulfur batteries. The improved electrochemical performances are attributed to the capping effect exerted by N-doping for polysulfides and high electrical conductivity of the carbon framework with highly conductive graphene. (C) 2016 Elsevier Ltd. All rights reserved.