• 文献标题:   Upright Standing Graphene Formation on Substrates
  • 文献类型:   Article
  • 作  者:   YUAN QH, HU H, GAO JF, DING F, LIU ZF, YAKOBSON BI
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • ISSN:   0002-7863
  • 通讯作者地址:   Hong Kong Polytech Univ
  • 被引频次:   30
  • DOI:   10.1021/ja2037854
  • 出版年:   2011

▎ 摘  要

We propose integrating graphene nanoribbons (GNRs) onto a substrate in an upright position whereby they are chemically bound to the substrate at the basal edge. Extensive ab initio calculations show that both nickel (Ni)- and diamond-supported upright GNRs are feasible for synthesis and are mechanically robust. Moreover, the substrate-supported GNRs display electronic and magnetic properties nearly the same as those of free-standing GNRs. Due to the extremely small footprint of an upright GNR on a substrate, standing GNRs are ideal building blocks for synthesis of subnanometer electronic or spintronic devices. Theoretically, standing GNR-based microchips with field-effect transistor (FET) densities up to 10(13) per cm(2) are achievable.