• 文献标题:   AgPd nanoparticles supported on reduced graphene oxide: A high catalytic activity catalyst for the transfer hydrogenation of nitroarenes
  • 文献类型:   Article
  • 作  者:   LIU XT, WANG CH, CHENG SS, SHANG NZ, GAO ST, FENG C, WANG C, QIAO YQ, WANG Z
  • 作者关键词:   agpd nanoparticle, sacrificial method, reduced graphene oxide, catalytic transfer hydrogenation, nitroarene
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Hebei Agr Univ
  • 被引频次:   5
  • DOI:   10.1016/j.catcom.2018.02.001
  • 出版年:   2018

▎ 摘  要

In this paper, well dispersed AgPd nanoparticles supported on reduced graphene oxide were fabricated by a simple nonnoble metal sacrificial method. Firstly, the Co-3(BO3)(2) and AgPd nanoparticles were co-deposited on the surface of reduced graphene oxide, then the Co-3(BO3)(2) was sacrificed by acid etching. Highly dispersed AgPd nanoparticles were obtained by using cobalt as the sacrificial agent to prevent AgPd nanoparticles from aggregation. The obtained catalyst furnish excellent catalytic activity and chemoselectivity for the catalytic transfer hydrogenation of nitroarenes using formic acid and ammonium formate as hydrogen source at room temperature. The homologous aniline derivatives were obtained with high yields.