• 文献标题:   A facile synthesis of graphene-metal (Pb, Zn, Cd, Mn) sulfide composites
  • 文献类型:   Article
  • 作  者:   FU XQ, JIANG TS, ZHAO Q, YIN HB
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   15
  • DOI:   10.1007/s10853-011-5890-0
  • 出版年:   2012

▎ 摘  要

We propose a general approach for the preparation of graphene-metal sulfide quantum dots (QDs) composites by pi-pi stacking of pyridine-capped metal sulfide QDs and chemically converted graphene (CCG) in aqueous solution. CCG sheets disperse stably in water without the assistance of dispersing agents, only by electrostatic repulsion. The aromatic structures of pyridine capped on metal sulfide QDs make these QDs dispersible in ethanol or water, and further introduce a pi-pi stacking interaction between CCG and QDs, and extend the conjugated structure of CCG. The structural details, formation mechanism, and textural properties of the resultant graphene-metal sulfide QDs composites are characterized by X-ray diffraction, UV-vis absorption, electron microscopy, and Raman scattering studies. The CCG-metal sulfide composites disperse stably in aqueous solution, allowing them to be potentially used in biological tissues and easy-to-form filtered films for further research and application.