• 文献标题:   Mesoporous Li3VO4/C Submicron-Ellipsoids Supported on Reduced Graphene Oxide as Practical Anode for High-Power Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   LI QD, WEI QL, SHENG JZ, YAN MY, ZHOU L, LUO W, SUN RM, MAI LQ
  • 作者关键词:  
  • 出版物名称:   ADVANCED SCIENCE
  • ISSN:   2198-3844
  • 通讯作者地址:   Wuhan Univ Technol
  • 被引频次:   50
  • DOI:   10.1002/advs.201500284
  • 出版年:   2015

▎ 摘  要

Despite the enormous efforts devoted to high-performance lithium-ion batteries (LIBs), the present state-of-the-art LIBs cannot meet the ever-increasing demands. With high theoretical capacity, fast ionic conductivity, and suitable charge/discharge plateaus, Li3VO4 shows great potential as the anode material for LIBs. However, it suffers from poor electronic conductivity. In this work, we present a novel composite material with mesoporous Li3VO4/C submicron-ellipsoids supported on rGO (LVO/C/rGO). The synthesized LVO/C/rGO exhibits a high reversible capacity (410 mAh g(-1) at 0.25 C), excellent rate capability (230 mAh g(-1) at 125 C), and outstanding long-cycle performance (82.5% capacity retention for 5000 cycles at 10 C). The impressive electrochemical performance reveals the great potential of the mesoporous LVO/C/rGO as a practical anode for high-power LIBs.