• 文献标题:   Reduction of silver nanoparticles onto graphene oxide nanosheets with N,N-dimethylformamide and SERS activities of GO/Ag composites
  • 文献类型:   Article
  • 作  者:   YANG YK, HE CE, HE WJ, YU LJ, PENG RG, XIE XL, WANG XB, MAI YW
  • 作者关键词:   graphene oxide, silver nanoparticle, n ndimethylformamide, surfaceenhanced raman scattering
  • 出版物名称:   JOURNAL OF NANOPARTICLE RESEARCH
  • ISSN:   1388-0764 EI 1572-896X
  • 通讯作者地址:   Hubei Univ
  • 被引频次:   69
  • DOI:   10.1007/s11051-011-0550-5
  • 出版年:   2011

▎ 摘  要

Silver nanoparticles (Ag NPs) have been homogeneously deposited onto graphene oxide (GO) nanosheets by an optimal method, in which N,N-dimethylformamide (DMF) as a co-dispersant of GO and reductant of sliver ions is added to an aqueous suspension of GO and AgNO3. GO nanosheets are uniformly covered by Ag NPs with a narrow size distribution and inter-particle gap. Raman signals of GO are greatly enhanced after deposition owing to the charge transfer interaction of GO with Ag NPs. The GO/Ag composite can be further utilized as an effective surface-enhanced Raman scattering (SERS) active substrate. Several new Raman bands and frequency shifts are clearly observed in using 4-aminothiophenol (4-ATP) as a Raman probe on GO/Ag compared to the normal Raman spectrum of solid 4-ATP. The Raman enhancement arises from a major electromagnetic effect and a minor chemical effect.