• 文献标题:   L-Cysteine-Assisted Synthesis of Cubic Pyrite/Nitrogen-Doped Graphene Composite as Anode Material for Lithium-ion Batteries
  • 文献类型:   Article
  • 作  者:   QIU WD, XIA J, ZHONG HM, HE SX, LAI SH, CHEN LP
  • 作者关键词:   pyrite, nitrogendoped graphene, electrochemical propertie, anode material, lithium ion batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Sun Yat Sen Univ
  • 被引频次:   34
  • DOI:   10.1016/j.electacta.2014.05.156
  • 出版年:   2014

▎ 摘  要

Transition-metal sulfides have received increasing attention as electrode materials for high-performance Lithium-ion Batteries (LIBs). However, most of them are suffering from poor cycling stability and rate capability. Herein we report a new and facile strategy for synthesizing FeS2/nitrogen-doped graphene (FeS2/N-G) composite which shows improved electrochemical performance as an anode material for LIBs. The as-prepared FeS2/N-G (1:2, molar ratio) composite exhibits reversible discharge and charge capacities of 979 and 920 mAh g(-1), respectively, with good cycling,performance and rate capability. SEM and TEM results show that the cubic FeS2 are uniformly distributed on the surface of the nitrogen-doped graphene nanosheets (N-GNS) in the composite. The superior electrochemical performance of FeS2/N-G composite as LIBs anode is attributed to their robust composite structure and the synergistic effects between cubic FeS2 and N-GNS. This synthesis approach could open up new opportunities in the design and fabrication of energy storage devices. (C) 2014 Elsevier Ltd. All rights reserved.