• 文献标题:   Ultra-dispersed island-like Co9S8 nanoparticles composed of nanosheets in-situ grown on nitrogen-doped graphene for asymmetric supercapacitor
  • 文献类型:   Article
  • 作  者:   WANG XZ, SU DC, XIAO YH, XU SG, FANG SM, CAO SK
  • 作者关键词:   co9s8, graphene, supercapacitor, composite
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   18
  • DOI:   10.1016/j.electacta.2018.10.059
  • 出版年:   2019

▎ 摘  要

Island-like Co9S8 nanoparticles composed of two-dimensional (2D) Co9S8 nanosheets in-situ grew and were dispersed evenly on the surface of 2D N-doping graphene (NGR), which produced the Co9S8@NGR nanocomposites using a simple solvothermal method. In this solvothermal process, graphene oxides were reduced and doped with nitrogen (N) simultaneously. The Co9S8@NGR nanocomposites delivered an ultra-high specific capacitance of 2992 Fg(-1) in a potential window of 0.5 Vat 1 A g(-1). Moreover, an asymmetric supercapacitor (ASC) constructed by Co9S8@NGR as the positive electrode and by activated carbon (AC) as the negative electrode showed the density of 88.81 W h kg(-1) at a power density of 0.63 kW kg(-1), the power density of 21.80 kW kg(-1) at the energy density of 30.30 W h kg(-1), and the favorable cycle stability with 80.61% specific capacity retention at a current density of 10 A g(-1) after 10000 cycles. (C) 2018 Elsevier Ltd. All rights reserved.