• 文献标题:   Few-layer graphene obtained by electrochemical exfoliation of graphite cathode
  • 文献类型:   Article
  • 作  者:   ZHOU M, TANG J, CHENG Q, XU GJ, CUI P, QIN LC
  • 作者关键词:  
  • 出版物名称:   CHEMICAL PHYSICS LETTERS
  • ISSN:   0009-2614 EI 1873-4448
  • 通讯作者地址:   Univ N Carolina
  • 被引频次:   71
  • DOI:   10.1016/j.cplett.2013.04.013
  • 出版年:   2013

▎ 摘  要

Few-layer graphene has been prepared by electrochemical intercalation of graphite cathode using Na+/dimethyl sulfoxide complexes as intercalation agent. By adding thionin acetate salt into the electrolyte, the exfoliated graphite is stabilized and further exfoliated into few-layer graphene. Raman and X-ray photoelectron spectra indicate that the graphene material has lower content of defects and oxygen functional groups compared with that obtained by chemically reducing graphene oxide. The graphene paper produced by filtration shows an electrical conductivity of 380 S m(-1), which is forty times larger than that of the graphene material produced by chemical reduction of thionin-stabilized graphene oxide. (C) 2013 Elsevier B. V. All rights reserved.