• 文献标题:   Joule Heating Characteristics of Emulsion-Templated Graphene Aerogels
  • 文献类型:   Article
  • 作  者:   MENZEL R, BARG S, MIRANDA M, ANTHONY DB, BAWAKED SM, MOKHTAR M, ALTHABAITI SA, BASAHEL SN, SAIZ E, SHAFFER MSP
  • 作者关键词:  
  • 出版物名称:   ADVANCED FUNCTIONAL MATERIALS
  • ISSN:   1616-301X EI 1616-3028
  • 通讯作者地址:   Univ London Imperial Coll Sci Technol Med
  • 被引频次:   45
  • DOI:   10.1002/adfm.201401807
  • 出版年:   2015

▎ 摘  要

The Joule heating properties of an ultralight nanocarbon aerogel are investigated with a view to potential applications as energy-efficient, local gas heater, and other systems. Thermally reduced graphene oxide (rGO) aerogels (10 mg cm(-3)) with defined shape are produced via emulsion-templating. Relevant material properties, including thermal conductivity, electrical conductivity and porosity, are assessed. Repeatable Joule heating up to 200 degrees C at comparatively low voltages (approximate to 1 V) and electrical power inputs (approximate to 2.5 W cm(-3)) is demonstrated. The steady-state core and surface temperatures are measured, analyzed and compared to analogous two-dimensional nanocarbon film heaters. The assessment of temperature uniformity suggests that heat losses are dominated by conductive and convective heat dissipation at the temperature range studied. The radial temperature gradient of an uninsulated, Joule-heated sample is analyzed to estimate the aerogel's thermal conductivity (around 0.4 W m(-1) K-1). Fast initial Joule heating kinetics and cooling rates (up to 10 K s(-1)) are exploited for rapid and repeatable temperature cycling, important for potential applications as local gas heaters, in catalysis, and for regenerable of solid adsorbents. These principles may be relevant to wide range of nanocarbon networks and applications.