• 文献标题:   Graphene Quantum-Dot-Doped Polypyrrole Counter Electrode for High-Performance Dye-Sensitized Solar Cells
  • 文献类型:   Article
  • 作  者:   CHEN LJ, GUO CX, ZHANG QM, LEI YL, XIE JL, EE SJ, GUAI GH, SONG QL, LI CM
  • 作者关键词:   graphene quantum dot, polypyrrole, platinumfree counter electrode, dyesensitized solar cell
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Southwest Univ
  • 被引频次:   100
  • DOI:   10.1021/am302938a
  • 出版年:   2013

▎ 摘  要

Herein graphene quantum dot (GQD), a graphene material with lateral dimension less than 100 nm, is explored to dope PPy on F-doped tin oxide glass as an efficient counter electrode for high-performance dye-sensitized solar cells (DSSCs). The GQDs-doped PPy film has a porous structure in comparison to the densely structured plain PPy, and displays higher catalytic current density and lower charge transfer resistance than the latter toward I-3(-)/I- redox reaction. The highest power conversion efficiency (5.27%) for DSSCs is achieved with PPy doped with 10% GQDs, which is comparable to that of Pt counter electrode-based DSSCs. This work provides an inexpensive alternative to replace platinum for DSSCs.