• 文献标题:   Iron pincer complex and its graphene oxide composite as catalysts for Suzuki coupling reaction
  • 文献类型:   Article
  • 作  者:   KUMAR LM, MISHRA P, BHAT BR
  • 作者关键词:   suzukimiyaura crosscoupling, ncn pincer, amino functionalized graphene oxide, catalysi, biaryl
  • 出版物名称:   JOURNAL OF SAUDI CHEMICAL SOCIETY
  • ISSN:   1319-6103 EI 2212-4640
  • 通讯作者地址:   Natl Inst Technol Karnataka
  • 被引频次:   3
  • DOI:   10.1016/j.jscs.2018.08.005
  • 出版年:   2019

▎ 摘  要

We report the synthesis of Fe-NCN pincer complex as homogenous catalyst and its composite by immobilizing the complex on amino functionalized graphene oxide as a heterogeneous catalyst for Suzuki coupling reactions. Both the complex and the composite were employed in catalyzing the Suzuki-Miyaura cross-coupling reaction between the aryl halide and phenyl boronic acid in acetonitrile solvent media with Cs2CO3 as a base. Effect of substitution over aryl halide was also investigated. Immobilization of the pincer complex had advantageous recovery and reuse of the catalyst as compared to its homogenous analog with no significant decrease in the catalytic efficiency. (C) 2018 King Saud University. Production and hosting by Elsevier B.V.