• 文献标题:   One-Pot Synthesis of Conducting Poly(3-methylthiophene)-Grafted-Graphene Nanosheets
  • 文献类型:   Article
  • 作  者:   LINGAPPPAN N, JEONG JH, PARK JM, LIM KT
  • 作者关键词:   graphene, polymer composite, poly 3methylthiophene, oxidative polymerization
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Pukyong Natl Univ
  • 被引频次:   2
  • DOI:   10.1166/jnn.2014.8455
  • 出版年:   2014

▎ 摘  要

We report a simple one-pot synthesis of graphene nanosheets wrapped poly(3-methylthiophene) (GNs-f-P3MT) composites. At first, natural graphite was oxidized using the Hummer's method followed by chemical reduction with hydrazine monohydrate to yield GNs. Subsequently, in-situ chemical oxidative polymerization of 3-methylthiophene was carried out to obtain noncovalently bonded GNs-f-P3MT composites. The morphology and microstructure of the composites together with pure graphene oxide and GNs were characterized using XPS, XRD, FT-IR, FESEM, HRTEM and TGA. The microscopic results indicated the homogeneous dispersion of GNs throughout the polymer matrix. Furthermore, thermogravimetric results illustrated that the addition of GNs into the P3MT matrix led to improvement in the thermal stability of the composites.