• 文献标题:   Investigating the Properties of Cetyltrimethylammonium Bromide/Hydroxylated Graphene Quantum Dots Thin Film for Potential Optical Detection of Heavy Metal Ions
  • 文献类型:   Article
  • 作  者:   ANAS NAA, FEN YW, YUSOF NA, OMAR NAS, RAMDZAN NSM, DANIYAL WMEMM
  • 作者关键词:   graphene quantum dot, cetyltrimethylammonium bromide, thin film, structural, optical, spr, heavy metal ion
  • 出版物名称:   MATERIALS
  • ISSN:  
  • 通讯作者地址:   Univ Putra Malaysia
  • 被引频次:   1
  • DOI:   10.3390/ma13112591
  • 出版年:   2020

▎ 摘  要

The modification of graphene quantum dots (GQDs) may drastically enhance their properties, therefore resulting in various related applications. This paper reported the preparation of novel cetyltrimethylammonium bromide/hydroxylated graphene quantum dots (CTAB/HGQDs) thin film using the spin coating technique. The properties of the thin film were then investigated and studied. The functional groups existing in CTAB/HGQDs thin film were confirmed by the Fourier transform infrared (FTIR) spectroscopy, while the atomic force microscope (AFM) displayed a homogenous surface of the thin film with an increase in surface roughness upon modification. Optical characterizations using UV-Vis absorption spectroscopy revealed a high absorption with an optical band gap of 4.162 eV. Additionally, the photoluminescence (PL) spectra illustrated the maximum emission peak of CTAB/HGQDs thin film at a wavelength of 444 nm. The sensing properties of the as-prepared CTAB/HGQDs thin film were studied using a surface plasmon resonance technique towards the detection of several heavy metal ions (HMIs) (Zn2+, Ni2+, and Fe3+). This technique generated significant results and showed that CTAB/HGQDs thin film has great potential for HMIs detection.